How does the fractional column work? Fractionating columnshelp to separate the mixture by allowing the mixed vapors to cool, condense, and vaporize again in accordance with Raoult's law. The vapor condenses on glass spurs (known as trays or plates) inside the column, and returns to the distilling flask, refluxing the rising distillate vapor.
How does a fractional column work?
How does the fractional column work? Fractionating columns help to separate the mixture by allowing the mixed vapors to cool, condense, and vaporize again in accordance with Raoult's law. The vapor condenses on glass spurs (known as trays or plates) inside the column, and returns to the distilling flask, refluxing the rising distillate vapor.
How does a fractionating column separate the mixture?
Fractionating columns help to separate the mixture by allowing the mixed vapors to cool, condense, and vaporize again in accordance with Raoult's law. The vapor condenses on glass spurs (known as trays or plates) inside the column, and returns to the distilling flask, refluxing the rising distillate vapor. Click to see full answer.
What are the factors that affect the column of fractionation?
The more volatile liquids will tend to push towards the top of the fractionating column, while lower boiling liquids will stay towards the bottom, giving a better separation between the liquids. Home Study Guides Science Math and Arithmetic History Literature and Language Technology
How does fractional distillation work?
In a conventional fractional distillation procedure, a liquid combination is heated in the distilling flask, and the resultant vapor rises up the fractionating column until it reaches the collector (see Figure 1).
How fractional distillation works step by step?
The steps of the process are:Evaporation. Crude oil is heated until it evaporates. Crude oil vapour is put into a fractionating column at the bottom and rises upwards.Condensation. The temperature is highest at the bottom of the column. ... Collection. The fractions are collected.
How does a fractionating column work crude oil?
heated crude oil enters a tall fractionating column , which is hot at the bottom and gets cooler towards the top. vapours from the oil rise through the column. vapours condense when they become cool enough. liquids are led out of the column at different heights.
What is the function of the fractionating column in this method?
The fractionating column is used to separate the liquids according to the order of their vaporisation so that they get separated as they are vaporised.
How are fractions separated in a fractionating column?
Fractional distillation separates a mixture into a number of different parts, called fractions. A tall fractionating column is fitted above the mixture, with several condensers coming off at different heights. The column is hot at the bottom and cool at the top.
How does crude oil separated into fractions?
Fractional distillation is used to separate crude oil into simpler, more useful fractions. A fraction of crude oil is a group of hydrocarbon molecules of similar size with similar boiling points . Their similar boiling points mean that they can be separated by fractional distillation.
How does fractional distillation separate crude oil?
Crude oil is separated by fractional distillation. Crude oil is heated to vaporize the different hydrocarbons in a tank which is cool at the top and hot at the bottom. The vapours then rise and the different hydrocarbons condense at their specific boiling points, allowing them to be separated.
Why is the fractionating column filled with glass rods?
The glass beads present in the fractionating column provide a large surface area for hot vapours to cool and condense repeatedly. The fractionating column is fitted in the neck of the distillation flask containing the mixture of liquids to be separated.
What happens to the vapor in a fractionating column?
The more volatile liquids will gradually move towards the top of the fractionating column, while lower boiling liquids will stay towards the bottom, giving a better separation between the liquids. The vapor eventually reaches the condenser, where it is cooled and then drips into the collection vessel.
How does fractional distillation separate compounds?
Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation to fractionate.
What is fractional distillation in simple words?
Fractional distillation means that a type of distillation that involves the separation of miscible liquids. The fractional distillation process involves repeated condensation and distillation. Usually, the separation of a mixture into component parts takes place in fractional distillation.
How does a liquid feed work?
A liquid feed containing the mixture of two or more liquids enters the column at one or more points. The liquid flows over the plates , and vapor bubbles up through the liquid via holes in the plates. As liquid travels down the column, the vapor comes in contact with it several times due to the multiple plates – a critical process in distillation ...
What is distillation in chemistry?
Distillation is a process used to separate a mixture of two (or more) components into its virgin state by heating the mixture to a temperature between their respective boiling points. For example, at atmospheric pressure, water boils at 212ºF and ethanol boils at about 176ºF. If the mixture of water and ethanol is heated to about 195ºF, ...
What Is a Fractionating Column and How Does It Work?
In its natural state, right after being extracted, crude oil is very rich in different components such as hydrocarbons with different molecular weight, and organic compounds.
First comes fractioning, then refining
The first substance to be eliminated from crude oil is salt, as it can be highly corrosive to the petrochemical plant.
Crude oil fractioning is a complex system
The type of distillation we described above is composed of different phases, and takes place inside a single column, which in turn has a complex structure, with different entry and exit points to allow the crude oil to be reinserted for a better efficiency of the process.

Overview
A fractionating column or fractional column is an essential item used in the distillation of liquid mixtures to separate the mixture into its component parts, or fractions, based on the differences in volatilities. Fractionating columns are used in small scale laboratory distillations as well as large scale industrial distillations.
Laboratory fractionating columns
A laboratory fractionating column is a piece of glassware used to separate vaporized mixtures of liquid compounds with close volatility. Most commonly used is either a Vigreux column or a straight column packed with glass beads or metal pieces such as Raschig rings. Fractionating columns help to separate the mixture by allowing the mixed vapors to cool, condense, and vaporize again in …
Industrial fractionating columns
Fractional distillation is one of the unit operations of chemical engineering. Fractionating columns are widely used in the chemical process industries where large quantities of liquids have to be distilled. Such industries are the petroleum processing, petrochemical production, natural gas processing, coal tar processing, brewing, liquified air separation, and hydrocarbon solvents production and simila…
See also
• Azeotropic distillation
• Batch distillation
• Continuous distillation
• Extractive distillation
• Laboratory glassware
External links
• Use of distillation columns in Oil & Gas
• More drawings of glassware including Vigreux columns
• Distillation Theory by Ivar J. Halvorsen and Sigurd Skogestad, Norwegian University of Science and Technology, Norway