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why chromium and copper has exceptional electronic configuration

by Caden Ritchie Published 3 years ago Updated 2 years ago

The order of filling of electrons occupying the 3d subshell gets concerned in chromium and copper and because of distress in 3d subshell, these elements possess exceptional configuration. The completely filled subshells are s2,p6,d10,f14 and half-filled subshells are s1,p3,d5,f7 containing additional stability.

Full Answer

Why do the electron configurations of chromium and copper disagree?

Why do the electron configurations of chromium and copper seem to disagree with what is expected according to the Aufbau principle? Some elements do not follow the Aufbau principle, there are some alternate ways that electrons can arrange themselves that give these elements better stability.

Why are copper and chromium exceptions to the 4s orbital?

Re: Why are Copper and Chromium exceptions? As others have said, the full 3d orbitals is more stable than a full 4s orbital, but this is only possible because the orbitals of the 4s and 3d orbitals have very close energy levels, so it is more stable for the electron to jump to fill the 3d orbitals rather than stay in the 4s orbitals.

Why is the orbital configuration of a chromium atom 3D?

The sole reason why Chromium takes up this kind of configurations is because of the very good stability of 3d (5) orbital. Stability arises due to half filled orbital. But the actual configurations goes as follows :

Why CR and CU are called exceptional configuration?

Hence, Cr and Cu are called exceptional configuration. Half filled or completely filled orbitals are more stable than those with one electron less. The d-orbital can occupy a maximum of 10 electrons. Since chromium had 4 electrons, which is one short of 5 electrons to get just hslf-filled. Click to see full answer.

Why are the 4s and 3D orbitals exceptions?

These two elements are exceptions because it is easier for them to remove a 4s electron and bring it to the 3d subshell, which will give them a half filled or completely filled subshell, creating more stability . Since the 4s orbital has a lot of electron repulsion, it easily donates an electron to the nearby 3d orbital.

Is a 3D orbital more stable than a 4S orbital?

As others have said, the full 3d orbitals is more stable than a full 4s orbital, but this is only possible because the orbitals of the 4s and 3d orbitals have very close energy levels, so it is more stable for the electron to jump to fill the 3d orbitals rather than stay in the 4s orbitals. Top.

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